Monolayers of Benzodithia-Crown-Ether Derivative: Surface Active and Photosensitive Properties
نویسنده
چکیده
Monolayers based on the novel multifunctional compound K29 (the amphiphilic and photosensitive derivative of dithiacrown-ethers) were obtained and investigated. The studied ion-selective and photosensitive properties of K29 in monolayers demonstrated its ability to form complexes with mercury cations which were detected by significant changes in the K29 monolayer isotherms and absorption spectra. Such obtained supramolecular systems are promising as models of the molecular organization and recognition processes at the interfaces.
منابع مشابه
Surface Plasmon Spectroscopic Detection of Saxitoxin
For the surface-optoelectronic study of Saxitoxin sensing, we fabricated selfassembled calix[4]arene derivative monolayers as the recognition-functional interfaces on a gold surface. An interaction study between Saxitoxin and calix[4]arene derivative monolayers were performed using surface plasmon resonance (SPR) spectroscopy. Among three calix[4]arene derivatives, calix[4]arene crown ether SAM...
متن کاملInfluence of a Crown Ether on the Spectral Properties of Triarylmethane Dyes in Aqueous and Micellar Environments
This study demonstrates the spectral data for two triarylmethane dyes, malachite green (MG) and crystal violet (CV) at room temperature. Effects of micellar environment, and crown ether addition on the spectral behaviour of the dyes were studied using absorption spectroscopic method. The dye-anionic surfactant interactions in micellar media were investigated. The chosen surfactants with differe...
متن کاملNew Hybrid Nanomaterial Derived from Immobilization of 4-Formyl Benzo-9-Crown-3 Ether onto the Mesopores of MCM-41
In this work, we report a new hybrid nanomaterial based on the immobilization of 4-formyl benzo-9-crown-3 ether (FB9C3) onto the mesopores of MCM-41. First, the mesoporous molecular sieve MCM-41 was covalently grafted with 3-aminopropyl triethoxysilane to give aminopropyl modified MCM-41 (AmpMCM-41). Reaction of this material with FB9C3 afforded the B9C3-AmpMCM-41 hybrid nanomaterial. The prepa...
متن کاملMonolayers of a novel ionoselective butadienyl dye.
The novel amphiphilic benzodithia-18-crown-6 butadienyl dye (1) forms relatively stable insoluble monolayers on distilled water (collapse pressure of 41 mN/m) and on aqueous subphases containing alkali metal or heavy metal salts (collapse pressures in the range of 27-38 mN/m, respectively). The dye 1 monolayer organization depends on chromophore association and interactions (especially complex ...
متن کاملBoron nitride substituted 12-crown-4 ether: Theoretical study of structural, thermochemical, and nonlinear optical properties
The structures and stability of 531 novel boron nitride substituted isomers of 12-crown-4 etherverified theoretically. For a collection of 23 selected BN isomers, structural geometry, vibrationalstability, energy gaps, natural bond population analysis, and nonlinear optical responses investigatedtheoretically. The changes of standard enthalpies for ionization reactions and electron affinityreac...
متن کامل